Hi,
Is it possible to rotate the roll axis on a rig without rotating the Joint in the same time??? I need to animate the fingers, but the rot axis are not properly aligned to the finger so I would need to rotate it in 2 axis to get the right rotation…
Then the problem with the fingers not being oriented properly should be coming from characterization. Was your character in a T-pose with the arms and fingers fully stretched (and the fingers straight and pointing outwards) ? When the bones in the skeleton are oriented properly and you follow the correct characterization process you should have no problems with efector orientation. Hope I was helpfull 
Dont remember if it was in T-pose when I characterized it, but it might be the problem…Thanks
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