hi leonard, i’m also interested in these kind of questions. on the “Science for CG”, it is explained as this :
" Selective specular reflections are possible only for metals, which results in tinted reflections. Conductors (metals) dont have subsurface reflection, only specular reflection. " with a nice pic (have a look).
i understand it as : highlight is a phenomen of surface.
when light arrives on a dialectic material (with reflective property), a part of is absorbed, another is absorbed in subsurface and reemitted (diffuse), but another part of the all spectrum is immediatly reflected : highlight with white reflective color.
with metals, there is only absorption and reflection. if we see a tinted highlight (gold or copper…) that means some part of the spectrum has been totally absorbed and the other immediatly reflected.
i’m not totally sure with all that so i would be interested if someonelse can complete or correct. 