I made an architecture specific forum in Renderman. and did test render there and comparing the result with Vray. I have been using vray for 7 years and when Renderman was made free to public , I had a chance to test it out.
both are capable of producing the same high quality result. though I am only familiar with Archviz, I am pretty sure both renderer are really fast. so in terms of render quality, I have no doubt Vray or renderman can do the job nicely.
it’s just… if u are working in ArchViz, then best weapon is to use Vray since there are TONS of 3D model u can buy or download are mostly available in Vray.
I like renderman so much but when it comes to downloadable asset on the net, Vray provide wayyy more availability. (see Archmodel from Volume 1 - 150 )
if you are working in ARchviz then its Vray obviously, if you are in Movie industry, then you would have to create every single asset one by one with your team, in which Renderman can save u a lot of time because the setting is simpler than Vray. (How I love Disney Shader). and btw, displacement in Renderman is super awesome.
Maxwell is extremely good too. the setting is so simple. layered material works really good and very easy to control. it has one disadvantage, super long render time. I use it in Rhino before gave up due to super long render time. its using light transit approach which simulate lights correctly as it is in real world (awesome reflection n chaustic effect. rendering Metal object is the best in Maxwell). it stores light data and u can change the light properties, its color, intensity, even turning on and off the light AFTER the rendering is done. honestly I think once the computer power is strong enough in the future, all renderer will go towards Light transit method.
I dont know much about arnold since I never use it but I heard its extremely good and capable of handling massive amount of geometry.
Thats all I can say,
happy renderinggggg